Wednesday, September 30, 2009
Algaecide
Algaecide is a chemical treatment for swimming pools, fish ponds and other 'water features' that kills algae. Algae are very small organisms that grow in water or very damp environments. Algae in pools and ponds can cause the water to become cloudy, and in some cases can form a scum over the surface that blocks the sunlight from the water. Algae is the cause of the peculiar 'red tide' phenomenon, in which the ocean appears to be covered in blood. Usually algae is unsightly, yet it can also be dangerous —- certain kinds of algae give off toxins that can be hazardous to humans, fish and plants.
Thursday, May 8, 2008
Ammonium bisulfite
Ammonium bisulfite is colorless crystals which are soluble in water। It is noncombustible. It is corrosive to aluminum. It is a strong irritant to skin and mucous membranes. It is toxic by skin absorption.
Pure ammonium bisulfite is a white crystalline solid. Commercially, however, aqueous liquid form (typically 60%) is common.
Ammonium bisulfite's reductive and sulfonating properties provide versatile applications. It is used as an oxygen scavenger to eliminate the dissolved oxygen in waste water and in பிபெஸ்
Ammonium bisulfite is a reductive bleaching agent. It reduces carbonyl and alcohol groups, which function as colorants of the substances. It is used in bleaching mechanical paper pulp, cotton, wool and kaolin clay. Additional applications include as a preservative (antioxidant) and a hair waving agent.
Ammonium bisulfite is used in industries concerned with leather processing, food and beverage processing, gas purification, water treatment to remove excess chlorine, textiles and pulp processing, and many others. It is used as a reducing agent in chemical manufacturing. It is an alternative to sulfur dioxide which is used in sterlization of equipment.
Sulfate (also spelled sulphate in Europe) is any chemical compound containing the SO42- ion related to sulfuric acid (H2SO4). Sulfates are salts or esters of sulfuric acid, formed by replacing one or both of the hydrogens with a metal or a radical as in sodium sulfate, Na2SO4. Sulfates in which both hydrogens are replaced are called normal sulfates. Bisulfate is a compound that has the HSO4- radical. Bisulfate (called also hydrogen sulfate or acid sulfate) is a compound formed by replacing only one hydrogen in sulfuric acid. Sulfite (also sulphite) is a compound that contain the sulfite ion SO32-. Sulfites are salts or esters of sulfurous acid (H2SO3), formed by replacing one or both of the hydrogens with a metal or a radical as in sodium sulfite, Na2SO3. Sulfites in which both hydrogens are replaced are called normal sulfites. Bisulfite is a compound that has the HSO3- radical. Bisulfate (called also hydrogen sulfite or acid sulfite) is a compound formed by replacing only one hydrogen in sulfurous acid. The term of 'meta' or 'pyro' is the chemical prefix for oxo acid formed through the loss of one water molecule (dehydration) from two molecules of ortho acid by heating. Pyrosulfuric acid is an example ( 2H2SO4 - H2O = H2S2O7). Ortho acid is the compound fully hydrated acid or its salts. Orthophosphoric acid is an example (2·H3PO4 = P2O5.3H2O), in contrast to the less hydrated form, pyrophosphoric acid (2·HPO3 = P2O5.H2O). Na2O5S2 is called sodium metabisulfite (2·HNaO3S - H2O). Sulfide is a compound having one or more sulfur atoms in which the sulfur is connected directly to a carbon, metal, or other nonoxygen atom; for example sodium sulfide, Na2S. Sulfide ion is S2- with oxidation number -2. Bisulfide ion is an anion formed by two sulfur atoms having an overall -2 charge, (S2)2-. Sulfamate is a salt of sulfamic acid (HSO3NH2). Calcium sulfamate Ca(SO3NH2)2 is an example.
Pure ammonium bisulfite is a white crystalline solid. Commercially, however, aqueous liquid form (typically 60%) is common.
Ammonium bisulfite's reductive and sulfonating properties provide versatile applications. It is used as an oxygen scavenger to eliminate the dissolved oxygen in waste water and in பிபெஸ்
Ammonium bisulfite is a reductive bleaching agent. It reduces carbonyl and alcohol groups, which function as colorants of the substances. It is used in bleaching mechanical paper pulp, cotton, wool and kaolin clay. Additional applications include as a preservative (antioxidant) and a hair waving agent.
Ammonium bisulfite is used in industries concerned with leather processing, food and beverage processing, gas purification, water treatment to remove excess chlorine, textiles and pulp processing, and many others. It is used as a reducing agent in chemical manufacturing. It is an alternative to sulfur dioxide which is used in sterlization of equipment.
Sulfate (also spelled sulphate in Europe) is any chemical compound containing the SO42- ion related to sulfuric acid (H2SO4). Sulfates are salts or esters of sulfuric acid, formed by replacing one or both of the hydrogens with a metal or a radical as in sodium sulfate, Na2SO4. Sulfates in which both hydrogens are replaced are called normal sulfates. Bisulfate is a compound that has the HSO4- radical. Bisulfate (called also hydrogen sulfate or acid sulfate) is a compound formed by replacing only one hydrogen in sulfuric acid. Sulfite (also sulphite) is a compound that contain the sulfite ion SO32-. Sulfites are salts or esters of sulfurous acid (H2SO3), formed by replacing one or both of the hydrogens with a metal or a radical as in sodium sulfite, Na2SO3. Sulfites in which both hydrogens are replaced are called normal sulfites. Bisulfite is a compound that has the HSO3- radical. Bisulfate (called also hydrogen sulfite or acid sulfite) is a compound formed by replacing only one hydrogen in sulfurous acid. The term of 'meta' or 'pyro' is the chemical prefix for oxo acid formed through the loss of one water molecule (dehydration) from two molecules of ortho acid by heating. Pyrosulfuric acid is an example ( 2H2SO4 - H2O = H2S2O7). Ortho acid is the compound fully hydrated acid or its salts. Orthophosphoric acid is an example (2·H3PO4 = P2O5.3H2O), in contrast to the less hydrated form, pyrophosphoric acid (2·HPO3 = P2O5.H2O). Na2O5S2 is called sodium metabisulfite (2·HNaO3S - H2O). Sulfide is a compound having one or more sulfur atoms in which the sulfur is connected directly to a carbon, metal, or other nonoxygen atom; for example sodium sulfide, Na2S. Sulfide ion is S2- with oxidation number -2. Bisulfide ion is an anion formed by two sulfur atoms having an overall -2 charge, (S2)2-. Sulfamate is a salt of sulfamic acid (HSO3NH2). Calcium sulfamate Ca(SO3NH2)2 is an example.
Sunday, December 30, 2007
Bentonite
Bentonite is an absorbent aluminium phyllosilicate generally impure clay consisting mostly of montmorillonite.
There are a few types of bentonites and their names depend on the dominant elements, such as K, Na, Ca, and Al. As noted in several places in the geologic literature, there are some nomenclatorial problems with the classification of bentonite clays.
Bentonite usually forms from weathering of volcanic ash, most often in the presence of water. However, the term bentonite, as well as a similar clay called tonstein, have been used for clay beds of uncertain origin.
For industrial purposes, two main classes of bentonite exist: sodium and calcium bentonite.
In stratigraphy and tephrochronology, completely devitrified (weathered volcanic glass) ash-fall beds are commonly referred to as K-bentonites when the dominant clay species is illite. Other common clay species, and sometimes dominant, are montmorillinite and kaolinite. Kaolinite dominated clays are commonly referred to as tonsteins and are typically associated with coal.
Sodium bentonite
Sodium bentonite expands when wet, possibly absorbing several times its dry mass in water. It is often used in drilling mud for oil and gas wells and for geotechnical and environmental investigations.
The property of swelling also makes sodium bentonite useful as a sealant, especially for the sealing of subsurface disposal systems for spent nuclear fuel and for quarantining metal pollutants of groundwater. Similar uses include making slurry walls, waterproofing of below-grade walls and forming other impermeable barriers (e.g. to plug old wells or as a liner in the base of landfills to prevent migration of leachate into the soil).
Sodium bentonite can also be "sandwiched" between synthetic materials to create geo-synthetic liners for the aforementioned purposes. This technique allows for more convenient transport and installation and it greatly reduces the volume of sodium bentonite required.
Calcium bentonite
Calcium bentonite may be converted to sodium bentonite and exhibit sodium bentonite's properties by a process known as "ion exchange". Commonly this means adding 5-10% of sodium carbonate to wet bentonite, mixing well, and allowing time for the ion exchange to take place.[citation needed]
Pascalite is a commercial name for the calcium bentonite clay.
Uses for both types
Much of bentonite's usefulness in the drilling and geotechnical engineering industry comes from its unique rheological properties. Relatively small quantities of bentonite suspended in water form a viscous, shear thinning material. Most often, bentonite suspensions are also thixotropic, although rare cases of rheopectic behavior have also been reported.
At high enough concentrations (~60 grams of bentonite per litre of suspension), bentonite suspensions begin to take on the characteristics of a gel (a fluid with a minimum yield strength required to make it move). For these reasons it is a common component of drilling mud used to curtail drilling fluid invasion by its propensity for aiding in the formation of mud cake.
Bentonite can be used in cement, adhesives, ceramic bodies, cosmetics and cat litter. Fuller's earth, an ancient dry cleaning substance, is finely ground bentonite, typically used for purifying transformer oil. Bentonite, in small percentages, is used as an ingredient in commercially designed clay bodies and ceramic glazes. Bentonite clay is also used in pyrotechnics to make end plugs and rocket nozzles, and can also be used as a therapeutic face pack for the treatment of acne/oily skin.
The ionic surface of bentonite has a useful property in making a sticky coating on sand grains. When a small proportion of finely ground bentonite clay is added to hard sand and wetted, the clay binds the sand particles into a moldable aggregate known as green sand used for making molds in sand casting. Some river deltas naturally deposit just such a blend of such clay silt and sand, creating a natural source of excellent molding sand that was critical to ancient metalworking technology. Modern chemical processes to modify the ionic surface of bentonite greatly intensify this stickiness, resulting in remarkably dough-like yet strong casting sand mixes that stand up to molten metal temperatures.
The same effluvial deposition of bentonite clay onto beaches accounts for the variety of plasticity of sand from place to place for building sand castles. Beach sand consisting of only silica and shell grains does not mold well compared to grains coated with bentonite clay. This is why some beaches are so much better for building sand castles than others.
The self-stickiness of bentonite allows high-pressure ramming or pressing of the clay in molds to produce hard, refractory shapes, such as model rocket nozzles. Indeed, to test whether a particular brand of cat litter is bentonite, simply ram a sample with a hammer into a sturdy tube with a close-fitting rod; bentonite will form a very hard, consolidated plug that is not easily crumbled.
Bentonite also has the interesting property of adsorbing relatively large amounts of protein molecules from aqueous solutions. It is therefore uniquely useful in the process of winemaking, where it is used to remove excessive amounts of protein from white wines. Were it not for this use of bentonite, many or most white wines would precipitate undesirable flocculent clouds or hazes upon exposure to warmer temperatures, as these proteins denature. It also has the incidental use of inducing more rapid clarification of both red and white wines.
bentonite is as a mud constituent for oil- and water- well drilling.
Its role is mainly to seal the borehole walls, to remove drill cuttings and to lubricate the cutting head. The special higher mud yield results in using less quantity of Bentonite for the same standard mud. This results in lesser requirement of Bentonite.
India Bentonite Mfg: http://www.ashapura.com/drilling.html
There are a few types of bentonites and their names depend on the dominant elements, such as K, Na, Ca, and Al. As noted in several places in the geologic literature, there are some nomenclatorial problems with the classification of bentonite clays.
Bentonite usually forms from weathering of volcanic ash, most often in the presence of water. However, the term bentonite, as well as a similar clay called tonstein, have been used for clay beds of uncertain origin.
For industrial purposes, two main classes of bentonite exist: sodium and calcium bentonite.
In stratigraphy and tephrochronology, completely devitrified (weathered volcanic glass) ash-fall beds are commonly referred to as K-bentonites when the dominant clay species is illite. Other common clay species, and sometimes dominant, are montmorillinite and kaolinite. Kaolinite dominated clays are commonly referred to as tonsteins and are typically associated with coal.
Sodium bentonite
Sodium bentonite expands when wet, possibly absorbing several times its dry mass in water. It is often used in drilling mud for oil and gas wells and for geotechnical and environmental investigations.
The property of swelling also makes sodium bentonite useful as a sealant, especially for the sealing of subsurface disposal systems for spent nuclear fuel and for quarantining metal pollutants of groundwater. Similar uses include making slurry walls, waterproofing of below-grade walls and forming other impermeable barriers (e.g. to plug old wells or as a liner in the base of landfills to prevent migration of leachate into the soil).
Sodium bentonite can also be "sandwiched" between synthetic materials to create geo-synthetic liners for the aforementioned purposes. This technique allows for more convenient transport and installation and it greatly reduces the volume of sodium bentonite required.
Calcium bentonite
Calcium bentonite may be converted to sodium bentonite and exhibit sodium bentonite's properties by a process known as "ion exchange". Commonly this means adding 5-10% of sodium carbonate to wet bentonite, mixing well, and allowing time for the ion exchange to take place.[citation needed]
Pascalite is a commercial name for the calcium bentonite clay.
Uses for both types
Much of bentonite's usefulness in the drilling and geotechnical engineering industry comes from its unique rheological properties. Relatively small quantities of bentonite suspended in water form a viscous, shear thinning material. Most often, bentonite suspensions are also thixotropic, although rare cases of rheopectic behavior have also been reported.
At high enough concentrations (~60 grams of bentonite per litre of suspension), bentonite suspensions begin to take on the characteristics of a gel (a fluid with a minimum yield strength required to make it move). For these reasons it is a common component of drilling mud used to curtail drilling fluid invasion by its propensity for aiding in the formation of mud cake.
Bentonite can be used in cement, adhesives, ceramic bodies, cosmetics and cat litter. Fuller's earth, an ancient dry cleaning substance, is finely ground bentonite, typically used for purifying transformer oil. Bentonite, in small percentages, is used as an ingredient in commercially designed clay bodies and ceramic glazes. Bentonite clay is also used in pyrotechnics to make end plugs and rocket nozzles, and can also be used as a therapeutic face pack for the treatment of acne/oily skin.
The ionic surface of bentonite has a useful property in making a sticky coating on sand grains. When a small proportion of finely ground bentonite clay is added to hard sand and wetted, the clay binds the sand particles into a moldable aggregate known as green sand used for making molds in sand casting. Some river deltas naturally deposit just such a blend of such clay silt and sand, creating a natural source of excellent molding sand that was critical to ancient metalworking technology. Modern chemical processes to modify the ionic surface of bentonite greatly intensify this stickiness, resulting in remarkably dough-like yet strong casting sand mixes that stand up to molten metal temperatures.
The same effluvial deposition of bentonite clay onto beaches accounts for the variety of plasticity of sand from place to place for building sand castles. Beach sand consisting of only silica and shell grains does not mold well compared to grains coated with bentonite clay. This is why some beaches are so much better for building sand castles than others.
The self-stickiness of bentonite allows high-pressure ramming or pressing of the clay in molds to produce hard, refractory shapes, such as model rocket nozzles. Indeed, to test whether a particular brand of cat litter is bentonite, simply ram a sample with a hammer into a sturdy tube with a close-fitting rod; bentonite will form a very hard, consolidated plug that is not easily crumbled.
Bentonite also has the interesting property of adsorbing relatively large amounts of protein molecules from aqueous solutions. It is therefore uniquely useful in the process of winemaking, where it is used to remove excessive amounts of protein from white wines. Were it not for this use of bentonite, many or most white wines would precipitate undesirable flocculent clouds or hazes upon exposure to warmer temperatures, as these proteins denature. It also has the incidental use of inducing more rapid clarification of both red and white wines.
bentonite is as a mud constituent for oil- and water- well drilling.
Its role is mainly to seal the borehole walls, to remove drill cuttings and to lubricate the cutting head. The special higher mud yield results in using less quantity of Bentonite for the same standard mud. This results in lesser requirement of Bentonite.
India Bentonite Mfg: http://www.ashapura.com/drilling.html
Tuesday, October 30, 2007
NMR-FACILITY at Bharathidasan University
NMR FACILITY
A modern analytical chemistry technique, Fourier Transform-Nuclear Magnetic Resonance (FT-NMR) spectroscopy is now made available by Bharathidasan University at its School of chemistry for use by researchers and Research and Development (industrial) personnel. The NMR facility is highly useful in structural identification of different class of organic compounds
Charges: 500 /- per hr. with a minimum of Rs.500 per sample for 1 D spectrum (1H, 13C,) extra charges for deuterated solvents other than CDCl3 and D2O. Educational and research institutions will pay 1/5th of the charges. Private and government small-scale industries will pay 3/5th of the charges. Full amount will be charged for private industries.
Model: Brucker AC 200 MHz
Nuclei that can be studied: 1H, 13C, 31P.
Sample required: 5-10 mg for 1H and 50- 100 mg for 13C.
Nature of compound: e.g., solubility, carcinogenic, radioactive, lachrymatory, explosive, hygroscopic (contemplated/ known) needs to be mentioned.
For more details contact: 0431-2407053 .
A modern analytical chemistry technique, Fourier Transform-Nuclear Magnetic Resonance (FT-NMR) spectroscopy is now made available by Bharathidasan University at its School of chemistry for use by researchers and Research and Development (industrial) personnel. The NMR facility is highly useful in structural identification of different class of organic compounds
Charges: 500 /- per hr. with a minimum of Rs.500 per sample for 1 D spectrum (1H, 13C,) extra charges for deuterated solvents other than CDCl3 and D2O. Educational and research institutions will pay 1/5th of the charges. Private and government small-scale industries will pay 3/5th of the charges. Full amount will be charged for private industries.
Model: Brucker AC 200 MHz
Nuclei that can be studied: 1H, 13C, 31P.
Sample required: 5-10 mg for 1H and 50- 100 mg for 13C.
Nature of compound: e.g., solubility, carcinogenic, radioactive, lachrymatory, explosive, hygroscopic (contemplated/ known) needs to be mentioned.
For more details contact: 0431-2407053 .
Sunday, June 17, 2007
Demulsifiers-Bottle Test1
Testing Procedure
The objective of a demulsifier “bottle test” is to investigate the performance of demulsifier in a series of tests that is designed to duplicate the conditions found in the actual production system as closely as possible.
Emulsions can be stabilised by various attributes of the fluids or process. Wax and mineral scale both of which could stabilise emulsions are some of the possible causes.
Three case histories that have been experienced by the Production Chemical are described to illustrate the problems that may occur. Please note there other factors – demulsifier overtreatment, chemical additions upstream, GOR of wells and shearing down hole or at the choke etc.
Wax stabilised emulsions are quite a common occurrence throughout the world. In Figure 1 examples from several West African Oilfield where wax is both precipitating as a wax layer and also producing a wax-stabilised emulsion can be seen.
Examples of Wax-Stabilised Emulsions from Several West African Oilfields
In several fields in Brunei and Eastern Malaysia the produced water is very low in salinity but does contain high concentrations of calcium and bicarbonate ions in solution. As the fluids are produced calcium carbonate scale is precipitated as very small crystals that are less than 5 microns in size. The fine scale particles “coat” the water-oil interface of the droplets of suspended water and effectively stabilise an emulsion. Before this mechanism was isolated, high concentrations of “conventional” demulsifiers were required to “break” the emulsion. In a quest for a more cost-effective treatment it was discovered that a demulsifier containing organic acids would chemically react with the calcium carbonate and de-stabilise the emulsion.
In the Netherlands a film-forming Imidazoline-based corrosion inhibitor was used on an annulus-batch treatment of the “sour” gas wells. The wells produced significant quantities of formation water and hydrocarbon condensate. It was found that the slugs of corrosion inhibitor produced an extremely stable water-in-condensate emulsion that was unresponsive to any known or blended demulsifier or high temperature (80°C). The solution to the problem was to change the corrosion inhibitor from an oil soluble, water dispersible product to a water-soluble, oil insoluble product. The emulsion problem “disappeared” with the change in corrosion inhibitor type.
These three emulsion stabilisation cases have been used to illustrate that emulsions can be produced by “man-made” events but that they can be treated by the optimum selection of demulsifier or a process change. It is necessary to understand all the production system to design an effective bottle test of demulsifiers.
The procedure developed for screening the demulsifiers contained numerous stages that were designed to provide pieces in the treatment jigsaw puzzle.
The first stage is to obtain a demulsifier-free representative crude oil sample. Sometimes this is very difficult to obtain due to the practicalities. This is often the case in demulsification studies and necessitates that a representative “blend” is made from the crude oil from different wells. Producing a two-phase sample of crude oil that can be poured into demulsifier testing settling tubes to ensure a reproducible sample is difficult to the point of impossible when there is “free water” present.
“Free Water” is the formation water that is not emulsified or dispersed in the oil phase and rapidly settles out under gravity to give a water layer. If a bulk oil sample is poured into several tubes different volumes of free water will be transferred and this is no good for comparative testing purposes.
The procedure adopted to obtain a reproducible Crude Oil when we have to collect the sample from the wellheads is as follows:
One litre or two and half litre samples of crude oils to be obtained from each well if possible or several wells. The wells that were selected provided a range of water-oil ratios, were from different production zones, variable temperatures and production rates.
The samples were heated to 40°C to provide a liquid crude oil and the free water from each sample was separated and retained. The “free water”-oil ratio, known as the “water-cut”, of each of the crude oil samples was determined.
The separated oil was blended together to produce a Composite Synthetic Blend.
The various water phases from the samples were combined to produce a composite water blend.
The free water was added to several demulsifier tubes in the proportion that was determined in the “water-cut” test and then the blended oil sample was added to the 100% mark of the tubes.
The samples to be heated if this happens in the process or the bottle test is to be run at the incoming temperature of the crude where the crude enters into the first separation vessel.
The “bottle test” is designed to duplicate, as far a possible, the actual process conditions. However it is not possible to simulate everything and it has been found over many years of worldwide testing that the concentration of demulsifier in the process can be different to that in the laboratory bottle test. The fist stage of testing is to “bench mark” the demulsifier that is currently used . Use the bench marking test this can range from 5ppm to 200ppm depending on the associated problems. . The objective of the bottle testing is not to make the treatment “easy” but rather to work at a concentration where the treatment just occurs at the higher dosage and is possibly not fully treated at the lower rate. It is then possible to see differences in performance and rank each chemical accordingly.
The next stage of the “bottle-test” is to evaluate all the chemicals. The test is comparative so all the chemicals need to be evaluated at the same time to ensure the testing conditions are identical,
Settling tests show the most effective intermediates. The points that are looked for are as follows:-:
Separated Water Visual Quality
Treated Oil Visual Quality
Interface Quality
Water Content of the “top oil”
Water Content of the “interface oil”
Salt Content of Top Oil
The objective of a demulsifier “bottle test” is to investigate the performance of demulsifier in a series of tests that is designed to duplicate the conditions found in the actual production system as closely as possible.
Emulsions can be stabilised by various attributes of the fluids or process. Wax and mineral scale both of which could stabilise emulsions are some of the possible causes.
Three case histories that have been experienced by the Production Chemical are described to illustrate the problems that may occur. Please note there other factors – demulsifier overtreatment, chemical additions upstream, GOR of wells and shearing down hole or at the choke etc.
Wax stabilised emulsions are quite a common occurrence throughout the world. In Figure 1 examples from several West African Oilfield where wax is both precipitating as a wax layer and also producing a wax-stabilised emulsion can be seen.
Examples of Wax-Stabilised Emulsions from Several West African Oilfields
In several fields in Brunei and Eastern Malaysia the produced water is very low in salinity but does contain high concentrations of calcium and bicarbonate ions in solution. As the fluids are produced calcium carbonate scale is precipitated as very small crystals that are less than 5 microns in size. The fine scale particles “coat” the water-oil interface of the droplets of suspended water and effectively stabilise an emulsion. Before this mechanism was isolated, high concentrations of “conventional” demulsifiers were required to “break” the emulsion. In a quest for a more cost-effective treatment it was discovered that a demulsifier containing organic acids would chemically react with the calcium carbonate and de-stabilise the emulsion.
In the Netherlands a film-forming Imidazoline-based corrosion inhibitor was used on an annulus-batch treatment of the “sour” gas wells. The wells produced significant quantities of formation water and hydrocarbon condensate. It was found that the slugs of corrosion inhibitor produced an extremely stable water-in-condensate emulsion that was unresponsive to any known or blended demulsifier or high temperature (80°C). The solution to the problem was to change the corrosion inhibitor from an oil soluble, water dispersible product to a water-soluble, oil insoluble product. The emulsion problem “disappeared” with the change in corrosion inhibitor type.
These three emulsion stabilisation cases have been used to illustrate that emulsions can be produced by “man-made” events but that they can be treated by the optimum selection of demulsifier or a process change. It is necessary to understand all the production system to design an effective bottle test of demulsifiers.
The procedure developed for screening the demulsifiers contained numerous stages that were designed to provide pieces in the treatment jigsaw puzzle.
The first stage is to obtain a demulsifier-free representative crude oil sample. Sometimes this is very difficult to obtain due to the practicalities. This is often the case in demulsification studies and necessitates that a representative “blend” is made from the crude oil from different wells. Producing a two-phase sample of crude oil that can be poured into demulsifier testing settling tubes to ensure a reproducible sample is difficult to the point of impossible when there is “free water” present.
“Free Water” is the formation water that is not emulsified or dispersed in the oil phase and rapidly settles out under gravity to give a water layer. If a bulk oil sample is poured into several tubes different volumes of free water will be transferred and this is no good for comparative testing purposes.
The procedure adopted to obtain a reproducible Crude Oil when we have to collect the sample from the wellheads is as follows:
One litre or two and half litre samples of crude oils to be obtained from each well if possible or several wells. The wells that were selected provided a range of water-oil ratios, were from different production zones, variable temperatures and production rates.
The samples were heated to 40°C to provide a liquid crude oil and the free water from each sample was separated and retained. The “free water”-oil ratio, known as the “water-cut”, of each of the crude oil samples was determined.
The separated oil was blended together to produce a Composite Synthetic Blend.
The various water phases from the samples were combined to produce a composite water blend.
The free water was added to several demulsifier tubes in the proportion that was determined in the “water-cut” test and then the blended oil sample was added to the 100% mark of the tubes.
The samples to be heated if this happens in the process or the bottle test is to be run at the incoming temperature of the crude where the crude enters into the first separation vessel.
The “bottle test” is designed to duplicate, as far a possible, the actual process conditions. However it is not possible to simulate everything and it has been found over many years of worldwide testing that the concentration of demulsifier in the process can be different to that in the laboratory bottle test. The fist stage of testing is to “bench mark” the demulsifier that is currently used . Use the bench marking test this can range from 5ppm to 200ppm depending on the associated problems. . The objective of the bottle testing is not to make the treatment “easy” but rather to work at a concentration where the treatment just occurs at the higher dosage and is possibly not fully treated at the lower rate. It is then possible to see differences in performance and rank each chemical accordingly.
The next stage of the “bottle-test” is to evaluate all the chemicals. The test is comparative so all the chemicals need to be evaluated at the same time to ensure the testing conditions are identical,
Settling tests show the most effective intermediates. The points that are looked for are as follows:-:
Separated Water Visual Quality
Treated Oil Visual Quality
Interface Quality
Water Content of the “top oil”
Water Content of the “interface oil”
Salt Content of Top Oil
Demulsifier bottle testing has a terminology all of its own that is used to describe the appearance of the water, oil and interface and various aspects of the testing.
Different engineers often use different terminology. The terms used during these bottle tests are as follows
Each of settling tube are placed in a tube rack and the visual appearance of the top oil, interface oil and interface are observed. The quality of each parameter for each treatment was subjectively ranked.
Using a special spring-loaded syringe fitted with a 15cm long canula, the oil is removed from the top oil of each settling tube. The canula has a sliding stop fitted that rests on the top rim of the settling tube and is locked in position to allow samples to be extracted from the same point in each settling tube and then placed in a centrifuge tube. The tube and contents are usually heated to 50°C and then placed in a heated centrifuge. The tubes are centrifuged at 3,500rpm for 5 minutes.
The volume of free water emulsion and solids are recorded. Two drops of a special demulsifier knock out drops are then added to each centrifuge, heated, shaken and re-centrifuged as before. The knock out drops can be the incumbent demulsifier cut back or a special product to break virtually any emulsion and will not “over-treat” the oil.
After the knock out treatment the separated water volume may have increased corresponding to the concentration of water in the emulsion.
The centrifuge test should be repeated for the interface-oil
Finally the salt-in-crude of the top-oil is sometimes determined. The equipment that is commonly used is a conductometric salt-in-crude analyser defined in the ASTM D-3230-97 procedure.
This is a quick and accurate technique, taking about 5 minutes per determination. The technique measures the conductivity of a solvent solution that has been mixed with a crude oil sample. This is should be related to a calibration curve corresponding to the ionic components in the formation water. The units used are pptb (pounds per thousand barrels of oil).
source: http://www.productionchemical.com/emulsions.htm
conversion-info
conversion-info
Be able to convert from one unit to another unit is very essential in chemical engineering as well as in other engineering disciplines. Unit conversion is required both in chemical plant operation and its design. It is a fundamental study in chemical engineering.Mastering unit conversion principles is a basic skill that should have by every chemical engineer. However, for several units with which he or she rarely uses in daily job may refer him or her to a handbook. Wow?sound boring!But?we have a good news from the internet. Now, there are many website providing unit conversion tools online. That?s good and very simple. Here are some website you may try to convert any kind of unit.
http://www.onlineconversion.com
http://www.unitconversion.org
http://www.digitaldutch.com/unitconverter
http://www.convert-me.com/en
http://www.sciencemadesimple.com/conversions.html
http://www.unit-conversion.info/
Be able to convert from one unit to another unit is very essential in chemical engineering as well as in other engineering disciplines. Unit conversion is required both in chemical plant operation and its design. It is a fundamental study in chemical engineering.Mastering unit conversion principles is a basic skill that should have by every chemical engineer. However, for several units with which he or she rarely uses in daily job may refer him or her to a handbook. Wow?sound boring!But?we have a good news from the internet. Now, there are many website providing unit conversion tools online. That?s good and very simple. Here are some website you may try to convert any kind of unit.
http://www.onlineconversion.com
http://www.unitconversion.org
http://www.digitaldutch.com/unitconverter
http://www.convert-me.com/en
http://www.sciencemadesimple.com/conversions.html
http://www.unit-conversion.info/
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